Help support MIT OpenCourseWare by shopping at Amazon.com! MIT OpenCourseWare offers direct links to Amazon.com to purchase the books cited in this course. Click on the Amazon logo to the left of any citation and purchase the book from Amazon.com, and MIT OpenCourseWare will receive up to 10% of all purchases you make. Your support will enable MIT to continue offering open access to MIT courses. |
Textbooks
Atkins, Peter and Loretta Jones. Chemical Principles: The Quest for Insight. 3rd ed. New York, NY: W.H. Freeman and Company, 2004. ISBN: 9780716757016.
———. Chemical Principles: The Quest for Insight/Student Study Guide and Solutions Manual. 3rd ed. New York, NY: W.H. Freeman and Company, 2004. ISBN: 9780716707400. (Bundled set. ISBN: 9780716762546.)
Grading
Grading criteria.
activities |
points |
Three 1-hour Exams (100 points each) |
300 |
Final Exam |
300 |
Homework |
100 |
Total |
700 |
Academic Honesty
It is expected that students will maintain the highest standards of academic honesty.
With respect to homework assignments, it is expected that no student will turn in work that is not his or her own by copying the work of another student or by using the work or solutions from this course given in previous years. Discussion of approaches to solving the homework problems after attempting to work the problems independently, however, is permitted and encouraged.
It is expected that during a test or examination, a student will not:
- Accept or use information of any kind from other students.
- Represent the work of another student as his or her own.
- Use aids to memory other than those expressly permitted by the examiner.
Following a test or examination, a student will not try to deceive teachers or graders by misrepresenting or altering his or her previous work. In advance of a test or exam, a student will not knowingly obtain access to the exam questions.
Departures from the above standards are contrary to fundamental principles of MIT and of the larger scientific community. Such departures are considered serious offenses for which disciplinary penalties, including suspension and expulsion, can be imposed.
Calendar
Lec #1-18 are taught by Professor Sylvia Ceyer. Lec #19-36 are taught by Professor Christopher Cummins.
Course calendar.
Lec # |
topics |
key dates |
1 |
Atomic Theory of Matter |
|
2 |
Discovery of Nucleus |
|
3 |
Wave-Particle Duality of Radiation and Matter |
|
4 |
Particle-Like Nature of Light |
|
5 |
Matter as a Wave |
Problem set 1 due |
6 |
Schrödinger Equation for H Atom |
|
7 |
Hydrogen Atom Wavefunctions |
Problem set 2 due |
8 |
P Orbitals |
|
9 |
Electronic Structure of Multielectron Atoms |
|
10 |
Periodic Trends in Elemental Properties |
Problem set 3 due |
11 |
Why Wavefunctions are Important? |
|
|
First Hour Exam |
|
12 |
Ionic Bonds - Classical Model and Mechanism |
|
13 |
Kinetic Theory - Behavior of Gases |
|
14 |
Distribution Molecular Energies |
Problem set 4 due |
15 |
Internal Degrees of Freedom |
|
16 |
Intermolecular Interactions |
|
17 |
Polarizability |
Problem set 5 due |
18 |
Thermodynamics and Spontaneous Change |
|
19 |
Molecular Description of Acids and Bases |
|
20 |
Lewis and Brønsted Acid-Base Concepts |
Problem set 6 due |
21 |
Titration Curves and pH Indicators |
|
|
Second Hour Exam |
|
22 |
Electrons in Chemistry: Redox Processes |
|
23 |
Cell Potentials and Free Energy |
|
24 |
Theory of Molecular Shapes |
Problem set 7 due |
25 |
Valence Bond Theory |
|
26 |
Molecular Orbital Theory |
|
27 |
Molecular Orbital Theory for Diatomic Molecules |
Problem set 8 due |
28 |
Molecular Orbital Theory for Polyatomic Molecules |
|
29-30 |
Crystal Field Theory |
Problem set 9 due on Lec #29 |
31 |
Color and Magnetism of Coordination Complexes |
|
|
Third Hour Exam |
|
32 |
Coordination Complexes and Ligands |
|
33 |
Ligand Substitution Reactions: Kinetics |
|
34 |
Bonding in Metals and Semiconductors |
Problem set 10 due |
35 |
Metals in Biology |
|
36 |
Nuclear Chemistry and the Cardiolite® Story |
|